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Abstract It has been suggested that Ba3In2O6might be a high-Tcsuperconductor. Experimental investigation of the properties of Ba3In2O6was long inhibited by its instability in air. Recently epitaxial Ba3In2O6with a protective capping layer was demonstrated, which finally allows its electronic characterization. The optical bandgap of Ba3In2O6is determined to be 2.99 eV in-the (001) plane and 2.83 eV along thec-axis direction by spectroscopic ellipsometry. First-principles calculations were carried out, yielding a result in good agreement with the experimental value. Various dopants were explored to induce (super-)conductivity in this otherwise insulating material. NeitherA- norB-site doping proved successful. The underlying reason is predominately the formation of oxygen interstitials as revealed by scanning transmission electron microscopy and first-principles calculations. Additional efforts to induce superconductivity were investigated, including surface alkali doping, optical pumping, and hydrogen reduction. To probe liquid-ion gating, Ba3In2O6was successfully grown epitaxially on an epitaxial SrRuO3bottom electrode. So far none of these efforts induced superconductivity in Ba3In2O6,leaving the answer to the initial question of whether Ba3In2O6is a high-Tcsuperconductor to be ‘no’ thus far.more » « less
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Charaev, I.; Bandurin, D. A.; Bollinger, A. T.; Phinney, I. Y.; Drozdov, I.; Colangelo, M.; Butters, B. A.; Taniguchi, T.; Watanabe, K.; He, X.; et al (, Nature Nanotechnology)
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Shen, Y.; Sears, J.; Fabbris, G.; Li, J.; Pelliciari, J.; Jarrige, I.; He, Xi; Božović, I.; Mitrano, M.; Zhang, Junjie; et al (, Physical Review X)
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Post, K W; Legros, A; Rickel, D G; Singleton, J; McDonald, R D; He, Xi; Božović, I; Xu, X; Shi, X; Armitage, N P; et al (, Physical Review B)Using time-domain terahertz spectroscopy in pulsed magnetic fields up to 31 T, we measure the terahertz optical conductivity in an optimally doped thin film of the high-temperature superconducting cuprate La1.84Sr0.16CuO4. We observe systematic changes in the circularly polarized complex optical conductivity that are consistent with cyclotron absorption of 𝑝-type charge carriers characterized by a cyclotron mass of 4.9𝑚e±0.8𝑚e and a scattering rate that increases with magnetic field. These results open the door to studies aimed at characterizing the degree to which electron-electron interactions influence carrier masses in cuprate superconductors.more » « less
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